Adsorption by Carbons by Eduardo J. Bottani, Juan M.D. Tascón

By Eduardo J. Bottani, Juan M.D. Tascón

This ebook covers the main major facets of adsorption via carbons, trying to fill the prevailing hole among the fields of adsorption and carbonaceous fabrics. either easy and utilized facets are offered. the 1st element of the e-book introduces actual adsorption and carbonaceous fabrics, and is through a piece in regards to the basics of adsorption by way of carbons. This ends up in improvement of a sequence of theoretical ideas that function an advent to the subsequent part during which adsorption is principally envisaged as a device to symbolize the porous texture and floor chemistry of carbons. specific recognition is paid to a couple novel nanocarbons, and the electrochemistry of adsorption through carbons is additionally addressed. ultimately, a number of very important technological functions of gasoline and liquid adsorption through carbons in components corresponding to environmental security and effort garage represent the final component to the booklet.

- the 1st ebook to handle the interaction among carbonaceous fabrics and adsorption
- contains vital environmental functions, comparable to the elimination of unstable natural compounds from polluted atmospheres
- covers either gas-solid and liquid-solid adsorption

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The simplest structural model for a microporous carbon is the slit-pore model, in which each pore is in the form of a parallel-sided and rigid graphitic slit. It is also assumed that the filling and emptying processes are not dependent on the spatial arrangement of the pores. , its chemical potential and enthalpy) is solely dependent on the distribution of 12 Chapter 1 Overview of Physical Adsorption by Carbons slit width. Obviously, this simple model cannot account for nonequilibrium effects such as delayed condensation or network percolation or for any significant variation of pore shape.

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In Characterization of Porous Solids VI (F. Rodriguez-Reinoso, B. McEnaney, J. Rouquerol, and K. Unger, eds). Elsevier, pp. 131–8. 34. B. and Quirke, N. (2001). Modeling gas adsorption in slit-pores using Monte-Carlo simulation. Mol. , 27, 295–321. 35. M. W. (1988). Assessment of microporosity. K. Unger, J. W. Sing, and H. Kral, eds). Elsevier, pp. 77–100. 36. H. C. (1976). Adsorption in slit-like and cylindrical micropores in the Henry’s law region. J. Chem. Soc. Faraday Trans. I, 72, 619–36. 37.

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