By Nikos Hadjichristidis, Akira Hirao, Yasuyuki Tezuka, Filip Du Prez
The sector of CMA (complex macromolecular structure) stands on the innovative of fabrics technological know-how, and has been a locus of extreme learn job lately. This e-book supplies an in depth description of the synthesis, characterization, and self-assembly of recently-developed complicated architectural fabrics with a few power purposes.
The architectural polymers, together with bio-conjugated hybrid polymers with poly(amino acid)s and gluco-polymers, star-branched and dendrimer-like hyperbranched polymers, cyclic polymers, dendrigraft polymers, rod-coil and helix-coil block copolymers, are brought bankruptcy through bankruptcy within the ebook. particularly, the booklet additionally emphasizes the subject of artificial breakthroughs by means of living/controlled polymerization given that 2000.
moreover, popular authors give a contribution on particular subject matters resembling helical polyisocyanates, metallopolymers, stereospecific polymers, hydrogen-bonded supramolecular polymers, conjugated polymers, and polyrotaxanes, that have attracted enormous curiosity as novel polymer fabrics with strength destiny functions. additionally, contemporary advances in reactive mixing accomplished with well-defined end-functionalized polymers are mentioned from an business viewpoint. subject matters on polymer-based nanotechnologies, together with self-assembled architectures and suprastructures, nano-structured fabrics and units, nanofabrication, floor nanostructures, and their AFM imaging research of hetero-phased polymers also are integrated.
Provides finished assurance of lately built complex architectural materialsContent:
Chapter 1 Cyclic and Multicyclic Topological Polymers (pages 1–19): Takuya Yamamoto and Yasuyuki Tezuka
Chapter 2 Ultrarapid ways to gentle Macromolecular Conjugation (pages 21–52): Andrew J. Inglis and Christopher Barner?Kowollik
Chapter three Synthesis and Self?Assembly of Hydrogen?Bonded Supramolecular Polymers (pages 53–95): Wolfgang H. Binder, Claudia Enders, Florian Herbst and Katharina Hackethal
Chapter four fresh artificial advancements in Miktoarm celebrity Polymers with greater than 3 various fingers (pages 97–132): Akira Hirao, Mayumi Hayashi, Tomoya Higashihara and Nikos Hadjichristidis
Chapter five certain Synthesis of Dendrimer?Like Star?Branched Polymers, a brand new classification of Well?Defined Hyperbranched Polymers (pages 133–167): Hee?Soo Yoo and Akira Hirao
Chapter 6 Arborescent Polymers with a Mesoscopic Scale (pages 169–194): Toufic Nabil Aridi and Mario Gauthier
Chapter 7 Hyperbranched Glyco?Conjugated Polymers (pages 195–227): Toshifumi Satoh and Toyoji Kakuchi
Chapter eight hugely Branched sensible Polymer Architectures by way of Click?Chemistry innovations (pages 229–265): Mieke Lammens and Filip Du Prez
Chapter nine residing Alkene Polymerization for Polyolefin Architectures (pages 267–316): Amelia M. Anderson?Wile, Joseph B. Edson and Geoffrey W. Coates
Chapter 10 Precision Polyolefins (pages 317–347): Erik B. Berda and Kenneth B. Wagener
Chapter eleven Polyhomologation: The dwelling Polymerization of Ylides (pages 349–376): Jun Luo and Kenneth J. Shea
Chapter 12 Phenylenevinylene Homopolymers and Block Copolymers through Ring?Opening Metathesis Polymerization (pages 377–393): Chin?Yang Yu and Michael L. Turner
Chapter thirteen Block Copolymers Containing Rod Segments (pages 395–429): Tomoya Higashihara and Mitsuru Ueda
Chapter 14 Synthesis of Well?Defined Poly(meth)acrylamides with different Stereoregularity via residing Anionic Polymerization (pages 431–460): Takashi Ishizone
Chapter 15 advanced Macromolecular Chimeras (pages 461–489): Hermis Iatrou, Marinos Pitsikalis, Georgios Sakellariou and Nikos Hadjichristidis
Chapter sixteen Self?Assembly and functions of Polyferrocenylsilane Block Copolymers (pages 491–526): George R. Whittell, Jessica Gwyther, David A. Rider and Ian Manners
Chapter 17 practical Polymeric Nanostructures ready through Self?Assembly and past (pages 527–567): Rachel okay. O'Reilly
Chapter 18 Morphologies of Block and Star?Branched Polymers with 3 elements (pages 569–591): Hirokazu Hasegawa
Chapter 19 Morphologies and Photophysical homes of Conjugated Rod–Coil Block Copolymers (pages 593–622): Chi?Ching Kuo, Cheng?Liang Liu and Wen?Chang Chen
Chapter 20 Bulk Self?Assembly of Linear Hybrid Polypeptide?Based Diblock and Triblock Copolymers (pages 623–645): Sebastien Lecommandoux
Chapter 21 AFM research of Comb (Co)Polymers with complicated Chain structure (pages 647–683): Michel Schappacher and Alain Deffieux
Chapter 22 Tunable Thermoresponsive Polymers by means of Molecular layout (pages 685–715): Richard Hoogenboom
Chapter 23 Fluorine?Containing Block Copolymers: Synthesis and alertness as a Template for Nanocellular and Porous constructions utilizing Supercritical Carbon Dioxide (pages 717–737): Hideaki Yokoyama and Kenji Sugiyama
Chapter 24 Architectural Polymers, Nanostructures, and Hierarchical constructions from Block Copolymers (pages 739–761): Ian Wyman and Guojun Liu
Chapter 25 Block Copolymer Nanostructured skinny motion pictures for complicated Patterning (pages 763–790): Michelle A. Chavis, Evan L. Schwartz and Christopher ok. Ober
Chapter 26 Ring Polymers: powerful Isolation and distinct houses (pages 791–821): Haskell W. Beckham
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Extra info for Complex Macromolecular Architectures: Synthesis, Characterization, and Self-Assembly
For mild and rapid cycloadditions with azides and; (b) PEGylation of enzymes via a copper-free azide–alkyne cycloaddition. J. Inglis and C. Barner-Kowollik, “Ultra rapid approaches to mild macromolecular conjugation,” Macromolecular Rapid Communications, 2010, 31, 14, 1247–1266. Ó Wiley-VCH Verlag GmbH & Co. , 2008). Such 4-dibenzocyclooctynols show similar reactivity to that of the DIFO derivatives of Bertozzi and are biocompatible. In model studies, various azides and cyclooctyne were mixed in an equimolar ratio and were found to undergo quantitative conversion into the corresponding 1,2,3-triazole within 30 min at ambient temperature.
And Washizuka, M. (2003c) Designing 8-shaped polymer topology by metathesis condensation with cyclic poly(THF) precursors having allyl groups. Macromolecules, 36, 12–17. , and Oike, H. (2004) Synthesis of polymeric topological isomers through electrostatic self-assembly and covalent fixation with star telechelic precursors. Macromolecular Rapid Communications, 25, 1531–1535. , and Adachi, K. (2007) Synthesis of polymeric topological isomers having y- and manacle-constructions with olefinic groups at designated positions.
Macromolecules, 41, 4416–4422. 2 Ultrarapid Approaches to Mild Macromolecular Conjugation Andrew J. Inglis and Christopher Barner-Kowollik Preparative Macromolecular Chemistry, Karlsruhe Institute of Technology (KIT), Engesserstraße 18, Geb. 1 Introduction The evolution of the synthetic macromolecular sciences has largely been driven by the increasing need for purposefully designed and precisely engineered materials for use in a wide variety of “high-demand” applications in fields ranging from biomedicine to the nanosciences.