By James E. Mark, Burak Erman, Mike Roland
Science and know-how of Rubber, moment Edition presents a basic survey of elastomers and an exam of rubberlike elasticity, with an emphasis on a unified remedy starting from actual conception to ultimate functions. Researchers in polymer technological know-how and engineering fields will locate assurance of contemporary advances, unsolved difficulties and projections, and processing.
* improved coverage
* up-to-date chapters that includes considerably extra information
* A unified therapy of the topic, with complete assurance starting from chemical features akin to elastomer synthesis and curing, via theoretical advancements and characterization of equilibrium and dynamic houses, to ultimate functions
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Technology and know-how of Rubber, moment variation presents a common survey of elastomers and an exam of rubberlike elasticity, with an emphasis on a unified remedy starting from actual idea to ultimate purposes. Researchers in polymer technological know-how and engineering fields will locate insurance of contemporary advances, unsolved difficulties and projections, and processing.
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Extra info for Science and Technology of Rubber
2 as determined by high-resolution gel permeation chromatography of ozonolysis products . The observed sequence distribution of monomer units was in accord with calculated values based on the monomer reactivity ratios . 2. 04; they decrease somewhat at lower temperatures but not to a great extent. These ratios are no doubt influenced by the marked water solubility of the acrylonitrile compared with that of butadiene. The foregoing r values lead to the following situation. In accordance with Eq.
For example, it can be deduced from Table XI that a copolymer of styrene and maleic anhydride (rxr2 => 0) would be strongly "alternating" , as it would be improbable to have a sequence of two styrene units and highly improbable to have a sequence of two maleic anhydride units. Also, it would obviously be extremely difficult to prepare a copolymer of styrene and vinyl acetate, because the latter monomer would be virtually excluded from the styrene polymerization. TABLE XI Monomer Reactivity Ratios for Free Radical Copolymerizations with Styrene (Μ,) Λ Monomer (M 2 ) Maleic anhydride 2,5-DichIorostyrene Methyl methacrylate Methyl acrylate Vinylidene chloride Diethyl maleate Vinyl acetate "Data taken Ref.
318]: Wx=xp*~\\-pY (6) Nx=p*-\\-p) (7) where Wx is the weight fraction of x-mers (chains having x units) and Nx is the mole fraction of Jt-mers. This distribution function can be used to calculate Mw, the weight-average molecular weight, as M w = M^LxWx. It can be shown that the foregoing summation leads to the relation (8) which then means that MJMn = \+p (9) Hence the weight/number ratio of chain lengths in these systems undergoes a steady increase with extent of reaction, approaching an ultimate value of 2.